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ELECTROCHEMICAL UNIT FOR THE
PRODUCTION OF VANADIUM REDOX FLOW BATTERY ELECTROLYTE
This robust and cost affordable electrochemical unit is built around
our PROTOTYPE
II or FLOWPRO
III and FLOWPRO
IV electrolyzers. This semi-pilot unit unit offers a total
electrode
surface area ranging from two square feet (0.186 m2)
up to ten square feet (0.929 m2). It is used for
pre-piloting trials and the small scale
commercial production of all
vanadium redox flow
battery electrolyte (VRFBE) or other redox battery electrolyte
chemistries [e.g., cerium (IV)/(III), iron (II)/(III)]. The nameplate
production
capacity starts at 18.9 L per day (5 gallons/day) up to 60L per day (15
gallons/day) of equimolar vanadium
redox flow battery electrolyte [i.e., 1.6
M V(total), 2.0 M H2SO4
(free) and with a molar
ratio V(IV)/V(III) = 1.0].
Models:
ELECTRO-UNIT
VRFBEX
- Design:
rectangular plates and frames combined with auxiliary tubular balancing
unit.
- Cell
construction
material: polyvinylchloride (PVC), chlorinated-polyvinyl
chloride (CPVC), polypropylene (PP).
- Piping
material
and size: CPVC and PVC [NPS Schedule #80].
- Configuration:
divided by ion exchange membranes in two or multiple compartments.
- Electrodes:
plates, three-dimensional (mesh and expanded metals).
- Gasketing:
EPDM or fluoroelastomers PVHF (VITON®).
- Electrolyte
circulation: anolyte and catholyte storage tanks,
turbulent promoters.
- Internal
flow circulation: flow-by, flow-through, manifolds,
distributors, serpentine.
- Electrodes
assembly: monopolar or bipolar stacks.
- Back
plates: aluminum 6061 T6, stainless steel AISI
316 tie rods and Belleville compression springs.
- Cooling:
coiled immersed chillers and plate heat exchanger.
- Pumping:
air-operated diaphragm pumps, centrifugal pumps, ball valves.
- Mixing:
inert gas sparging, impeller, in-line static mixer.
- Electrolyte
holding tanks: (2 x 5 gallons) up to (2 x 15 gallons).
- Instrumentation:
pH, ORP, temperature, and toroidal conductivity probes, pressure
gauges, rotameters.
- Electrical
connection: copper C101 busbars, copper cables AWG. No.
"1/0" to No. "3/0" (106 to 212 kcmil).
- Use:
indoor unit mounted on heavy steel duty cart (1200 lb.) with spill
containment trays.
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COMPLETE ELECTROCHEMICAL UNITS
FOR PRE-PILOTING OR SMALL SCALE PREPARATIVE UNITS
These complete electrochemical units offer a total electrode surface
area ranging
from four square feet (0.371 m2) up to
fifty (50) square feet (4.645 m2).
These are commonly used for pre-piloting various electrochemical
processes
either in alkaline
or acidic electrolytes. When equipped with electrolytes holding tanks
they allow to operate in recirculating mode. Impellers,
pumps, valves,
rotameters, strainers, filters, can be also provided. Internal or
external heating could be ensured by installing PTFE-coated or quartz
immersed
heaters to resist corrosion and harsh operating conditions.
Models: ELECTRO-UNIT
RX - ELECTRO-UNIT CX - ELECTRO-UNIT
DX - ELECTRO-UNIT
TX
- Types:
rectangular or cylindrical tanks with conical bottom, plate and frames,
tubular and coaxial with separator.
- Cell
construction
material:
Polyvinylchloride (PVC), chlorinated-polyvinyl chloride (CPVC),
polypropylene (PP).
- Piping
material
and size: CPVC, PVC [NPS Schedule #80], stainless steel,
PFA.
- Configuration:
undivided, divided with two or more compartments.
- Compartment
access:
open access, partially or entirely closed.
- Electrodes:
plates, rods, tubes, three-dimensional (mesh, expanded metal, felt, and
wool).
- Electrolyte
circulation: anolyte and/or catholyte storage tanks with
inlet and outlet,
turbulent promoters.
- Internal
flow circulation: flow-by, flow-through, distributor,
serpentine.
- Electrodes
assembly: monopolar, bipolar.
- Back
plates:
aluminum 6061 T6, stainless steels AISI 304 or AISI 316, and titanium
ASTM Grade 2 and 5.
- Heating
& Cooling:
immersed heaters, and heat exchangers.
- Pumping:
air-operated diaphragm pumps, centrifugal pumps, valves,
rotameters.
- Mixing:
gas sparging, impeller, in-line static mixer.
- Purification
of electrolyte: connection to ion exchange (IX) columns.
- Electrolyte
holding tanks: from 10 gallons up to 55 gallons or
connected fo FIBC containers (252-279 gallons).
- Solids
removal: inline filters or strainers, filter-presses, or
disk centriguges.
- Instrumentation:
pH, ORP, temperature, and toroidal conductivity probes, pressure
gauges, rotameters.
- Electrical
connection: copper C101 busbars, copper cables AWG. No.
"1/0" to No. "3/0" (106 to 212 kcmil).
- Uses:
Indoor or outdoor units mounted either on carts, platforms, skids or
containers (40-FEQ).
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PROTOTYPE
SCALE ELECTROLYZERS
The prototype
electrolyzers offer a total electrode surface area
ranging
from one square foot (929 cm2) up to ten square
feet (0.929 m2).
These are commonly used for testing various electrochemical processes
either in alkaline
or acidic electrolytes or redox flow battery stacks (e.g., vanadium
(IV)/(III), cerium (IV)/(III), iron (II)/(III), and other chemistries).
Eventually, impellers, pumps, valves,
rotameters, strainers, filters, can be also provided with immersed
heater or small heat exchangers.
Models:
TUBLAR II -
CIRCELL
II - PROTOTYPE
II - FLOWPRO
III - FLOWPRO IV
- Types:
rectangular tank, plate and frames, tubular, conical
- Cell
construction
material:
Polyvinylchloride (PVC), Chlorinated-Polyvinyl chloride (CPVC),
Polymethylmetacrylate (PMMA), Polycarbonate (PC), Polypropylene (PP),
PEEK
- Gasket
materials:
EPDM, Fluoroelastomers (VITON®).
- Piping
material
and size: CPVC, PVC, stainless steel, PFA.
- Compartment
access:
open access or entirely closed.
- Electrodes:
plates, rods, tubes, three-dimensional (mesh, expanded metal, felt, and
wool).
- Electrolyte
circulation: anolyte and/or catholyte inlet and outlet,
turbulent promoters.
- Internal
Flow circulation: flow-by, flow-through, distributor,
serpentine.
- Electrodes
assembly: monopolar, bipolar.
- Back
plates:
aluminum 6061 T6, stainless steels AISI 304 or AISI 316, and titanium
ASTM Gr. 2 and 5.
- Assembling:
clamps, hexagonal head bolts, washers and nuts, compression springs,
and tie rods.
- Heating:
immersed heater, heat exchanger.
- Pumping:
air-operated diaphragm pumps, centrifugal pumps, valves,
rotameters.
- Mixing:
gas sparging, impeller, in-line static mixer.
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LABORATORY
SCALE ELECTROLYZERS
The small scale
electrolyzers offer a total electrode surface area ranging
from
only 10 cm2 up to 400 cm2.
These are mainly used
for laboratory screening tests and scoping studies either in alklaine
or acidic
electrolytes. Eventually, anolyte and catholyte auxiliary tanks can be
also provided with immersed heater but it is usually cheaper for the
customer to purchase directly the ancillary equipment himself.
Models:
RECTLAB III -
RECTLAB IV
- RECTLAB V
- Types:
plate and frame, rectangular compartment, tubular
- Cell
construction
material:
Polyvinylchloride (PVC), Chlorinated-Polyvinyl chloride (CPVC),
Polymethylmetacrylate (PMMA), Polycarbonate (PC), Polypropylene (PP),
PEEK.
- Gasket
materials:
EPDM, Fluoroelastomers.
- Compression
fittings material and size: stainless steel, titanium,
PFA, with
tubing outer diameter.
- Compartment
access:
open access or totally closed
- Electrodes:
plates, rods, tubes, three-dimensional (mesh, expanded metal, felt, and
wool).
- Electrolyte
circulation options: peristaltic pump, anolyte and/or
catholyte
inlet and outlet,
turbulent promoters.
- Back
plates:
aluminum, stainless steel, and titanium.
- Assembling:
clamps, bolts and nuts.
- Heating:
immersed heater, heat exchanger.
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CYLINDRICAL ELECTROLYZER FOR
BENCHMARKING
OF ELECTRODES
These small scale
electrolyzers offer a total electrode surface area ranging
from
only 10 cm2 up to 100 cm2.
These are mainly used for laboratory screening tests for the
benchmarking of coupons of commercial electrodes either in alkaline
or acidic electrolytes. The clear design allows to vizualise the gas
evolution.
Models:
CYLAB II
- CYLAB
III
- Types:
cylindrical
- Cell
construction
material:
Clear Polyvinylchloride (PVC),
Polymethylmetacrylate (PMMA), Polycarbonate (PC).
- Gasket
materials:
EPDM, Fluoroelastomers.
- Compression
fittings material and size: PFA with tubing outer diameter.
- Compartment
access:
open access.
- Electrodes:
rods, and tubes
- Electrolyte
circulation: electrolyte inlet and outlet.
- Heating:
immersed heater.
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ORDERING
INFORMATION - Upon ordering,
the client must
provide his requirements to tailor
the suitable electrolyzer among the important parameters, these are
listed as follows:
- Cell
construction
material: Polyvinylchloride (PVC), Chlorinated-Polyvinyl
chloride (CPVC), Polymethylmetacrylate (PMMA), Polycarbonate (PC),
Polypropylene (PP), PEEK.
- Gasket
materials:
EPDM, Fluoroelastomers.
- Compression
fittings material and size: stainless steel, titanium,
PFA, with
tubing outer diameter.
- Compartment
access:
open or closed
- Electrodes:
plates, rods, tubes, three-dimensional (mesh, expanded metal, felt,
wool)
- Electrolyte
circulation: anolyte and/or catholyte inlet and outlet,
turbulent promoters.
- Backplates:
aluminum, stainless steel, and titanium.
- Assembling:
clamps, bolts and nuts, tie rods.
- Heating:
immersed heater, heat exchanger.
- Ancillary
equipments: pumps, impeller, mixer, valves, filters.
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For quotations, technical
inquiries and purchase orders please contact us: electrodes@electrochem-technologies.com or sales@electrochem-technologies.com |